OK, I'm not sure you are referring to samples.
You sound like you just want your own sounds.
And the best way to do this is learn how synths work.
Pick a nice synth like albino. IT can make lush warm pad sounds, sharp stabby bass hits, growling basslines, piercing leads - the works.
You need to learn about ADSR envelopes which govern the basic properties of the sound, then about synthesis in general - what waves sounds like what, the use of filters to shape sound, then how arpeggiators can be used to overlay effects, change pitch, LFOs - all sorts.
You could do a lot worse than buy this book.
http://www.amazon.co.uk/Quick-Guide-...832842-7278830
Sure you can find it cheaper somewhere
If you want your tracks to be your own you need to design your own sounds.
Samples just refer to recorded audio. I think you are looking for sound design, not samples.